کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1332798 | 979053 | 2006 | 7 صفحه PDF | دانلود رایگان |
Nonstoichiometric spinel oxides, LiAlxMn2−xO4−δ (x=0.1,0.2x=0.1,0.2), were synthesized under controlled partial pressure of oxygen, and their elecrochemical performances were investigated. As an Al content increases, solubility limit of the oxygen nonstoichiometry, δ , increased, while partial molar enthalpy ΔH¯O2 of the formation of oxygen nonstoichiometry decreased.Cycle performance of LiAlxMn2−xO4 showed significant improvement comparing with that of LiMn2O4 cathode. However, the decrease of theoretical capacity was accompanied with Al doping. Nonstoichiometric LiAlxMn2−xO4−δ showed the increase in capacity with keeping good cycle performances as well as stoichiometric LiAlxMn2−xO4. Although the introduction of oxygen nonstoichiometry leads to the increase of Mn3+ which is known as Jahn–Teller ion, DSC curves for LiAlxMn2−xO4−δ showed no exothermic peak due to phase transition arising from Jahn–Teller distortion around room temperature.
Defect introduction into spinel.Figure optionsDownload as PowerPoint slide
Journal: Journal of Solid State Chemistry - Volume 179, Issue 11, November 2006, Pages 3534–3540