Synthesis and structure determination of copper perrhenate, CuReO4

Copper(I) perrhenate, CuReO4, has been synthesized as a single-phase sample in sealed silica tubes at 500–800 °C, and its structure was determined for the first time by single-crystal X-ray diffraction. CuReO4 forms a new structure type derived from the diamond-structure and crystallizes in space group I41cd with lattice parameters a=13.6965(5) Å and c=7.7729(5) Å, Z=16 (rotation method data acquisition using ω and ϕ scans, R1=0.0191, wR2=0.0403). Cu and Re atoms are tetrahedrally coordinated by O atoms, these tetrahedra are corner-shared, forming spirally twisted rings of 4-6-8-10-MeO4 like SixOy-rings in some silicon dioxide modifications or aluminosilicates. According to low-temperature powder X-ray diffraction and differential thermal analysis, CuReO4 shows no phase transition down to 80 K and up to its melting point, 703 K.

Crystal structure of CuReO4 with tetrahedral coordination of Cu(I) and Re(VII) atoms represents a new structure type related to some silicon dioxides.Figure optionsDownload as PowerPoint slide