کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1334273 1500229 2016 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A {CoII9CoIII3} dodecanuclear cluster based on o-vanillin oxime: Synthesis, structures and properties
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
A {CoII9CoIII3} dodecanuclear cluster based on o-vanillin oxime: Synthesis, structures and properties
چکیده انگلیسی

A new dodecanuclear cluster [CoII9CoIII3(MeOsalox)6(OAc)15(H2O)6]·2MeCN·2H2O (1) (H2MeOsalox = 3-methyloxysalicylaldoxime) was synthesized under solvothermal conditions and characterized by IR, elemental analyses (EA), single-crystal X-ray diffraction and powder XRD. Magnetic investigations reveal that complex 1 exhibits antiferromagnetic interactions between the cobalt centers.

One mixed-valence cobalt(II/III) dodecanuclear cluster bridged by doubly deprotonated o-vanillin oxime and acetate anions has been assembled. Antiferromagnetic interactions between the cobalt ions are observed.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polyhedron - Volume 111, 17 June 2016, Pages 156–160
نویسندگان
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