Palladium(II) complexes with 2-acetylamino-5-mercapto-1,3,4-thiadiazolate (amta) ligands: Molecular structures of the all trans dipalladium “paddlewheel” Pd2(μ-amta)4 and Pd(κ1-amta)2(κ2-dppe)

► All-trans paddlewheel complex. ► Palladium heterocyclic thionate complexes. ► Flexible ligand binding.