کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1336215 | 1500223 | 2016 | 7 صفحه PDF | دانلود رایگان |
Seven chiral dioxidomolybdenum(VI) complexes with tridentate Schiff bases were synthesized by monocondensation of S(+)-1-amino-2-propanol with salicylaldehyde and its derivatives. One- (1H, 13C) and two-dimensional (COSY, gHSQC and NOESY) NMR, IR, CD and UV–Vis spectroscopy were used for detailed characterization of the new molybdenum(VI) compounds. After optimization of the reaction conditions, the catalytic activities of these complexes were tested for the oxidation of olefins, i.e. styrene and cyclohexene, with aqueous 30% H2O2 or tert-butyl hydroperoxide (TBHP) as an oxidant. Moreover, the molybdenum(VI) Schiff base complexes were also able to catalyze the oxidation of prochiral sulfides [PhSR (R = Me, Bz)] to optically active sulfoxides in the presence of aqueous 30% H2O2.
Seven chiral dioxidomolybdenum(VI) complexes with tridentate Schiff bases were synthesized by the monocondensation of S(+)-1-amino-2-propanol with salicylaldehyde and its derivatives. The catalytic activities of these complexes were tested in the oxidation of olefins using aqueous 30% H2O2 or tert-butyl hydroperoxide (TBHP) as an oxidant. Moreover, these catalysts are able to catalyze the oxidation of prochiral sulfides to optically active sulfoxides in the presence of aqueous 30% H2O2.Figure optionsDownload as PowerPoint slide
Journal: Polyhedron - Volume 117, 15 October 2016, Pages 352–358