کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1336347 1500225 2016 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
2D coordination polymer composed of 1D {NiII(μ-O)(μ-H2O)NiII}n ferromagnetic chains: Modulation of magnetic properties based on dehydration and rehydration
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
2D coordination polymer composed of 1D {NiII(μ-O)(μ-H2O)NiII}n ferromagnetic chains: Modulation of magnetic properties based on dehydration and rehydration
چکیده انگلیسی

Synthesis, single-crystal structure and magnetic properties of a 2D coordination compound [Ni(1,3-ADA)(H2O)]n (1) is reported which exhibits tunable magnetic behavior based on dehydration–rehydration. 1 shows ferromagnetic (FM) interaction between NiII ions. Combined detailed experimental and theoretical studies reveal that FM interaction arises due to “orthogonal” magnetic orbitals, which become distorted in desolvated state and suppress the FM interaction.

Synthesis, single-crystal structure and magnetic properties of a 2D coordination compound [Ni(1,3-ADA)(H2O)]n (1) is reported which exhibits tunable magnetic behavior based on dehydration–rehydration. 1 shows ferromagnetic (FM) interaction between NiII ions. Combined experimental and theoretical studies reveal that FM interaction arises due to “orthogonal” magnetic orbitals, which become distorted in desolvated state and suppress the FM interaction.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polyhedron - Volume 115, 5 September 2016, Pages 276–281
نویسندگان
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