کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1336347 | 1500225 | 2016 | 6 صفحه PDF | دانلود رایگان |
Synthesis, single-crystal structure and magnetic properties of a 2D coordination compound [Ni(1,3-ADA)(H2O)]n (1) is reported which exhibits tunable magnetic behavior based on dehydration–rehydration. 1 shows ferromagnetic (FM) interaction between NiII ions. Combined detailed experimental and theoretical studies reveal that FM interaction arises due to “orthogonal” magnetic orbitals, which become distorted in desolvated state and suppress the FM interaction.
Synthesis, single-crystal structure and magnetic properties of a 2D coordination compound [Ni(1,3-ADA)(H2O)]n (1) is reported which exhibits tunable magnetic behavior based on dehydration–rehydration. 1 shows ferromagnetic (FM) interaction between NiII ions. Combined experimental and theoretical studies reveal that FM interaction arises due to “orthogonal” magnetic orbitals, which become distorted in desolvated state and suppress the FM interaction.Figure optionsDownload as PowerPoint slide
Journal: Polyhedron - Volume 115, 5 September 2016, Pages 276–281