کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1339090 | 979692 | 2010 | 8 صفحه PDF | دانلود رایگان |
The synthesis of new water soluble N-alkylated derivatives of 1,3,5-triaza-7-phosphaadamantane is presented. The compounds were characterized by means of NMR and IR spectroscopy, mass spectrometry, high resolution mass spectrometry, elemental analysis and X-ray diffraction analysis. The water solubility of these compounds was found to be up to an astonishing 1450 g/L. Several different reactions were performed utilizing these highly interesting compounds as starting materials. It was shown that the substitution of the counter ion can be performed easily. Also transformations at the PTA framework were possible, as shown by an ester cleavage example. To prove that the resulting PTA derivatives are competent as ligands for transition metals, gold(I) complexes were synthesized, using Au(tht)Cl as the metal source. The resulting gold(I) complexes were characterized by 1H NMR and IR spectroscopy, mass and high resolution mass spectrometry or elemental analysis.
New highly water soluble mono-N-alkylated PTA salts were synthesized starting from PTA and alkyl bromides or triflates. Their subsequent transformations, exchange of the counter ion and application as ligands in gold(I) complexes were successfully performed. Detailed studies on their water solubility were also carried out.Figure optionsDownload as PowerPoint slide
Journal: Polyhedron - Volume 29, Issue 8, 27 May 2010, Pages 1925–1932