کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
13416930 1841355 2020 24 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Conductometric investigation of ceftriaxone disodium in aqueous solutions of 1-propanol and 2-propanol
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Conductometric investigation of ceftriaxone disodium in aqueous solutions of 1-propanol and 2-propanol
چکیده انگلیسی
Often common organic solvents have been used in extraction and purification of ceftriaxone disodium from aqueous solution. Therefore, in this study the conductometric properties of ceftriaxone disodium were investigated in aqueous solutions of 1-propanol and 2-propanol at T/K = (288.15-308.15). The conductivities data were analysed by Fuoss-Onsager conductivity equation. The obtained results indicate that the molar conductivity increases with temperature. Also, the molar conductivity increases with increasing concentration of 1-propanol and 2-propanol. The activation enthalpy of charge transfer is calculated from the temperature dependency of molar conductivity. The activation enthalpy of charge transfer in water is lower than that of aqueous solutions of 1-propanol and 2-propanol. The calculated Walden products reveal that ion-solvent interactions in aqueous solutions of 1-propanol and 2-propanol are weaker than that of water.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: The Journal of Chemical Thermodynamics - Volume 142, January 2020, 105972
نویسندگان
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