کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1383193 | 1500621 | 2016 | 10 صفحه PDF | دانلود رایگان |
• New composites of PLA/EVA blends with cellulose fibres were prepared by melt mixing.
• The composites showed improved adhesion and dispersion of fibres in the blend matrix.
• Crystallization behaviour and morphology are controlled by the polymers miscibility.
• Composites properties can be tuned by varying blend composition and fibres content.
• PLA ternary composites display advantageous processability and mechanical properties.
The effect of addition of an ethylene-vinyl acetate copolymer modified with glycidyl methacrylate (EVA–GMA) on the structure and properties of poly(lactic acid) (PLA) composites with cellulose micro fibres (CF) was investigated. Binary (PLA/CF) and ternary (PLA/EVA–GMA/CF) composites obtained by melt mixing in Brabender mixer were analysed by SEM, POM, WAXS, DSC, TGA and tensile tests. The miscibility and morphology of PLA/EVA–GMA blends were first examined as a function of composition: a large rise of PLA spherulite growth rate in the blends was discovered with increasing the EVA–GMA content (0–30 wt%) in the isothermal crystallization both from the melt and the solid state. PLA/EVA–GMA/CF ternary composites displayed improved adhesion and dispersion of fibres into the matrix as compared to PLA/CF system. Marked changes of thermodynamic and tensile parameters, as elastic modulus, strength and elongation at break were observed for the composites, depending on blend composition, polymer miscibility and fibre-matrix chemical interactions at the interface.
Journal: Carbohydrate Polymers - Volume 137, 10 February 2016, Pages 515–524