کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1385421 | 982446 | 2010 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Thermoplastic starch plasticized by an ionic liquid
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Thermoplastic starch (TPS) plasticized by 1-butyl-3-methylimidazolium chloride ([BMIM]Cl) was obtained by melt processing. The resulting electrically conductive TPS samples were less hygroscopic than glycerol plasticized TPS samples. Despite this lower water uptake, [BMIM]Cl seems to be intrinsically a more efficient plasticizer of starch. [BMIM]Cl plasticized TPS samples show a much higher elongation at break in the rubbery state than the glycerol plasticized TPS samples. Their unusually low rubbery Young's modulus for thermoplastic starch (0.5 MPa) suggests a strong reduction of hydrogen bonds between the starch chains due to the presence of the ionic liquid. A detailed IR spectroscopy analysis supports this interpretation.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Carbohydrate Polymers - Volume 82, Issue 2, 5 September 2010, Pages 256–263
Journal: Carbohydrate Polymers - Volume 82, Issue 2, 5 September 2010, Pages 256–263
نویسندگان
Abdulkader Sankri, Abdellah Arhaliass, Isabelle Dez, Annie Claude Gaumont, Yves Grohens, Denis Lourdin, Isabelle Pillin, Agnès Rolland-Sabaté, Eric Leroy,