کد مقاله کد نشریه سال انتشار مقاله انگلیسی ترجمه فارسی نسخه تمام متن
1400940 1501692 2016 6 صفحه PDF سفارش دهید دانلود کنید
عنوان انگلیسی مقاله ISI
Synthesis, structures, and fluorescence properties of two d-d heterometallic cluster-based complexes constructed by N-(phosphonomethyl) iminodiacetic acid
ترجمه فارسی عنوان
سنتز، ساختار و خواص فلورسانس دو مجموعه مبتنی بر خوشه heterometallic d تا d ساخته شده توسط N- (phosphonomethyl) اسید iminodiacetic
کلمات کلیدی
مجموعه Heterometallic؛ ساختار بلوری؛ ویژگی فلورسانس
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
چکیده انگلیسی


• Two novel d-d heterometallic cluster-based complexes were synthesized.
• They were constructed by H4PMIDA multifunctional ligand.
• The complex 1 exhibits 1D heteronuclear molecular chain structure.
• The complex 2 exhibits is a zero-dimensional heteronuclear molecular cluster.
• Their solid-state fluorescence properties have also been investigated at room temperature.

Two novel d-d heterometallic cluster-based complexes constructed by N-(Phosphonomethyl)imino-diacetic acid (H4PMIDA) multifunctional ligand, [Cu2Zn2(PMIDA)2(H2O)3]·3H2O(1), [ZnNi14(PMIDA)6(H2O)18]·(NO3)6·15H2O(2), have been synthesized under hydrothermal conditions and characterized by elemental analyses, IR spectra, thermal analyses, and single-crystal X-ray diffraction. The complex 1 is one-dimensional heteronuclear molecular chain, which is further extends into a 3D supramolecular network through very extensive OH⋯O hydrogen bonds. The compound 2 is a rare novel zero-dimensional heteronuclear molecular cluster, which is further extends into a 3D supramolecular network through very extensive OH⋯O hydrogen bonds. Moreover, the solid-state fluorescence properties of the two complexes have also been investigated at room temperature.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 1125, 5 December 2016, Pages 296–301
نویسندگان
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