کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1487150 1510694 2016 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Vibrational modes of chalcopyrite CdGeAs2 crystal
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Vibrational modes of chalcopyrite CdGeAs2 crystal
چکیده انگلیسی


• We get the phonon frequencies and their symmetry assignments of CdGeAs2 by first-principles calculations.
• The low-temperature polarized-Raman-scattering spectra of CdGeAs2 crystal were obtained.
• Comparing with the calculations, Raman active vibrational modes have been identified.
• We give a systematic analysis and deduce effective charge and dielectric constants.

The optical-phonon spectra of CdGeAs2 were investigated by low temperature polarized Raman scattering. According to vibrational modes of ZnS-type materials and selection rules of Raman scattering, all Raman active vibrational modes in the Brillouin-zone (BZ) center of CdGeAs2 predicted from group-theory arguments were identified and artificially grouped in three energy bands, including 45–94, 158–215 and around 260 cm−1. Based on the Lyddane-Sachs-Teller (LST) relation and measured refractive indices, the low-frequency dielectric constant ε(0) is estimated to be 15.04 and shows good agreement with the previous tests and predictions.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Research Bulletin - Volume 81, September 2016, Pages 107–113
نویسندگان
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