Evaluating the potential of a new titania precursor for the synthesis of mesoporous Fe-doped titania with enhanced photocatalytic activity

Mesoporous Fe (III) doped TiO2 nanoparticles with an anatase phase were prepared by using a stable precursor potassium hexafluorotitanate as Ti source for the first time and its physical as well as photocatalytic properties were compared with that of Fe doped titania prepared from the most common Ti source titanium isopropoxide. FeSO4·7H2O and Fe (NO)3·9H2O were used for doping titania with Fe (III). Physicochemical properties of the samples were characterized by XRD, XPS, FTIR, Raman spectroscopy, N2 adsorption–desorption isotherms, UV–vis diffuse reflectance spectroscopy. EDX confirms the presence of Fe. DRS and TEM reveals that doping has taken place. It was found that Fe-doped nanostructured titania prepared from potassium hexafluorotitanate was much more effective in the photocatalytic decomposition of bromocresol green than undoped nanostructured titania as well as commercial titania.

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► Synthesis of mesoporous titania and Fe-doped mesoporous titania.
► Characterization of the photocatalysts by XRD, XPS, TEM, TGA, FTIR, EPR etc.
► Photocatalytic decomposition of the dye bromocresol green.