کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1489994 | 992315 | 2012 | 4 صفحه PDF | دانلود رایگان |
Mesoporous carbons (MCs) with nanosheet-like walls have been prepared as electrodes for lithium-ion batteries by a simple one-step infiltrating method under the action of capillary flow. The influence of heat treatment temperature on the surface topography, pore/phase structure and anode performances of as-prepared materials has been investigated. The results reveal that melted liquid-crystal polycyclic aromatic hydrocarbons could be anchored on liquid/silica interfaces by molecule engineering. After carbonization, the nanosheets are formed as the pore walls of MCs and are perpendicular to the long axis of pores. The anode properties demonstrate that C-1200 displays higher reversible capacitance than those treated in higher temperature. The rate performances of C-1200 and C-1800 are similar and more excellent than that of C-2400. These improved lithium ion anode properties could be attributed to the nanosheet-like walls of MCs which can be influenced by the heat treatment temperature.
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► Mesoporous carbons possess unique nanosheet-like pore walls which can be changed by heat treatment.
► Lithium ion anode properties of mesoporous carbons could be influenced by the nanosheet-like walls.
► Mesoporous carbons with nanosheet-like walls exhibit enhanced electrochemical properties LIBs.
Journal: Materials Research Bulletin - Volume 47, Issue 8, August 2012, Pages 2104–2107