کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1492083 | 992369 | 2008 | 7 صفحه PDF | دانلود رایگان |
Spinel Co3O4 octahedra synthesized by a facile redox-precipitation method were investigated for the complete oxidation of methane. XRD analysis showed that the spinel structural Co3O4 octahedra had a relatively strong (1 1 1) diffraction peak as compared with that of the irregular shaped Co3O4 nanoparticles prepared by a conventional precipitation method. The results of methane combustion test demonstrated that the Co3O4 octahedra had no catalytic activity at 300–500 °C, while the Co3O4 irregular nanoparticles were highly active at the same reaction conditions. HRTEM studies revealed that the Co3O4 octahedra were predominantly exposed by the low Miller-index {1 1 1} facets with the lowest surface energy, and the Co3O4 irregular nanoparticles were exposed by various crystal facets. The results exhibited that the {1 1 1} facets with the low surface energy of the Co3O4 octahedra resulted in the inert catalytic activity in the methane oxidation reaction.
Journal: Materials Research Bulletin - Volume 43, Issue 11, 3 November 2008, Pages 2912–2918