کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
151331 | 456469 | 2010 | 9 صفحه PDF | دانلود رایگان |
Organically modified mesoporous silica materials have been prepared by direct co-condensation of styrylethyl-trimethoxysilane (STETMOS) and tetraethyl-orthosilicate (TEOS) in one-pot synthesis. The polymerizable nature of the styryl-containing precursor induces the formation of anchored polystyrene blocks on the silica surface, which are amenable to be functionalized with acid groups via sulfonation. The resultant organosulfonic-modified mesostructured silica materials exhibit hexagonal long-range mesoscopic arrangement with extended surface areas and narrow mean pore size distributions. Upon sulfonation a high number of sulfonic-acid sites have been introduced on the silica-anchored polystyrene-type organic moieties, thus providing strong acid sites embedded in a hydrophobic microenvironment. The catalytic performance of these strongly acidic hydrophobic materials has been assessed and compared with commercial catalysts in three different acid-catalyzed reactions. Two of them are acid strength-demanding reactions such as acylation of anisole with acetic anhydride and Fries rearrangement of phenyl acetate. The third one, based on the esterification of oleic acid with n-butanol, is a catalytic test wherein the hydrophobic nature of the catalyst surface plays an essential role. As result of these catalytic tests, the sulfonated polystyrene-modified hybrid materials have been shown as versatile and highly active acid heterogeneous catalysts, especially in hydrophobicity-demanding systems.
Journal: Chemical Engineering Journal - Volume 161, Issue 3, 15 July 2010, Pages 388–396