کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1516704 | 1511585 | 2010 | 6 صفحه PDF | دانلود رایگان |
This paper describes the synthesis and characterization of self-assembled organic–inorganic layered perovskite compounds, (C6H5-CnH2n-NH3)2PbBr4 (n=1–4). the effect of the number of carbon atoms of the alkyl chain length (n) on optical properties has been studied. (C6H5-CnH2n-NH3)2PbBr4 films fabricated by spin-coating are microcrystalline form, single phase and oriented with the c-axis. Crystallinity, the maximum PL intensity and the lifetime of exciton emissions varied with the number of carbon atoms. the lowest-energy exciton splits into a few fine-structure levels at low temperatures. Time-resolved photoluminescence spectra reveal that (C6H5-CnH2n-NH3)2PbBr4 shows both singlet and triplet excitons. with decreasing temperature, triplet exciton emissions become dominant for (C6H5-CnH2n-NH3)2PbBr4 (n=1–3), while (C6H5-C4H8-NH3)2PbBr4 shows mainly singlet exciton emissions. The intersystem crossing from excited singlet state to triplet state plays an important role in the relaxation process of excitons.
Journal: Journal of Physics and Chemistry of Solids - Volume 71, Issue 5, May 2010, Pages 797–802