کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1604919 | 1516204 | 2017 | 7 صفحه PDF | دانلود رایگان |
• The phosphor BaZnSiO4: Eu2+/Tm2+/Yb2+ can be prepared in air.
• The self-reduction of RE3+ to RE2+ result from the defect chemistry at Ba2+ sites.
• BaZnSiO4 can stabilize low-valence ions is due to its three-dimensional network.
• The white-emitting phosphor BaZnSiO4:0.03Eu show a superior synthesis route.
Nominal composition phosphors BaZnSiO4:RE (RE = Eu, Tm, Sm, Yb) were synthesized by the conventional solid-state method in air (oxidizing atmosphere, OA) and under 10%H2/90%N2 flow (reductive atmosphere, RA) conditions, respectively. Self-reduction phenomenon, which is a valence change from trivalent rare-earth ions (RE3+) to corresponding divalent state (RE2+) without reducing agent, were observed in the samples of Eu/Tm/Yb-doped BaZnSiO4 but have not observed in Sm-doped samples. Compared with RA condition, the ca. percent of the reductive concentration of Eu2+/Tm2+/Yb2+ in the phosphors BaZnSiO4 prepared in OA condition are 21%, 15% and 35%, respectively. It was found that both of BaZnSiO4:Eu and BaZnSiO4:Tm prepared in air show greatly broad band emission peak at 500 nm under the excitation of ultraviolet (UV), which indicated they are potential phosphors for UV-based LED. The factors which are related to self-reduction degree have been also discussed. The successful synthesis of BaZnSiO4:RE2+/3+ phosphors in air provides a new route to obtain other novel orthosilicate-based materials.
The self-reduction ability of RE (RE = Eu/Tm/Yb/Sm) in BaZnSiO4-based phosphors prepared in air was compared and explained. The white-emitting of BaZnSiO4:0.03Eu prepared in oxidizing atmosphere shows a potential environmentally friendly route to obtain phosphor for UV-based LED.Figure optionsDownload as PowerPoint slide
Journal: Journal of Alloys and Compounds - Volume 690, 5 January 2017, Pages 267–273