کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1607023 | 1516232 | 2016 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Origin of the strong optical nonlinearity of tellurium oxide-based compounds: The specific case of BaTe2O6
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
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چکیده انگلیسی
This paper is a contribution to the understanding of the crystal chemistry origin of the strong nonlinear optical properties of tellurium oxide-based compounds. The particular case of the BaTe2O6 (BaTeIVTeVIO6) phase has been investigated. The structure refinement using single crystal X-ray diffraction confirms that the TeIV atom is located in an unclassical TeO5 environment with one exceptionally short Te-O bond (1.82Â Ã
) and four long ones (2.12Â Ã
). The vibrational analysis points out that in this environment, from the spectrochemical point of view, the short bond is at the origin of a quasi-isolated TeIVO2+ molecular ion whereas the four longer bonds traduce weak interactions. Relationships have been established between the TeIV-O bond lengths and the Ï(3) susceptibility. The four long bonds, belonging practically to the xz-plane and involving the TeIV d-orbitals contribution, are at the origin of the high Ï(3)xxxx and Ï(3)zzzz values (30.0 and 44.3Â ÃÂ 10â13Â esu respectively). The short Te-O bond, directed along the y-direction, is responsible for the lower Ï(3)yyyy value (3.2Â ÃÂ 10â13Â esu). This study is the first obvious confirmation for a real crystal lattice of the high superiority of the nonlinear polarizability of the weak intermolecular Te-O bonds over that of the strong molecular Te-O ones.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 661, 15 March 2016, Pages 92-99
Journal: Journal of Alloys and Compounds - Volume 661, 15 March 2016, Pages 92-99
نویسندگان
D. Hamani, A. Plat, M. Colas, J. Cornette, O. Masson, A.P. Mirgorodsky, P. Thomas,