کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1612086 | 1516304 | 2014 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A novel preparation method and magnetic properties of NaZn13-type La(Fe, Si)13 compounds
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The single-phase NaZn13-type La(Fe,Si)13 compounds have been successfully synthesized by using a novel stoichiometry chemical ratio 1:11 of La and (Fe, Si). By this method, the as-cast compounds directly formed into NaZn13-type single phase from arc-melting when the Si content in the range of 2.2 to 2.4, which is the first time to obtain NaZn13-type single phase without any heat treatments. Meanwhile, when the Si content x ⩽ 1.4, all the compounds crystallize in the NaZn13-type cubic structure with small amounts of α-Fe impurity phase after annealed at 1373 K for 100 h. Among them, the LaFe9.8Si1.2 compound shows a thermal and field-induced first-order phase transition around its transition temperature. Its maximal magnetic entropy-change reaches to 14.8 J/kg K under a field change of 1.5 T, showing an excellent magnetic refrigeration property. Thus, the chemical ratio of 1:11 as a new stoichiometry provides a novel and rapid preparation method for single-phase NaZn13-type La(Fe,Si)13 compounds with excellent properties.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 589, 15 March 2014, Pages 416-419
Journal: Journal of Alloys and Compounds - Volume 589, 15 March 2014, Pages 416-419
نویسندگان
Lihong Bao, Wei Wei, Wendi Fan, O. Tegus,