Physical and chemical characterization and method for the decontamination of clays for application in cosmetics

• Physical-chemical clays I, II, III and IV originating from sand extraction residue
• Establishment of an effective method of microbial decontamination of clay samples
• Viability of incorporating clays decontaminated vehicles for cosmetic use

Clays are materials originated from rock decomposition, made up of clay minerals and non-clayish minerals. Their applicability in the field of cosmetics depends on their chemical and mineralogical composition. In view of their huge bioburden there is the need to submit them to effective decontamination before they are incorporated into cosmetics. The present work involved the characterization of four different samples of clays originated from the sand extraction residue of mining activities in the hinterland of São Paulo state, Brazil. Characterization was performed with the aid of tools like X-ray fluorescence (XRF), X-ray diffraction (XRD), thermogravimetric analysis (TGA/DTA), particle size distribution by laser dispersion, surface area (BET method) and Fourier transform infrared spectroscopy (FTIR). Besides, it aims to evaluate the bioburden of these clays, as well as to propose a method for the decontamination of these samples. The average particle diameter varied from 3.6 to 24.1 μm, kaolinite and illite being the main mineralogical phases to be identified. The proposed method for decontamination employed a combination of ethanol 70% and dry heat at 120 °C in an oven for 24 h. The decontamination was effective in reducing samples bioburden, leaving the clays within the limits required for cosmetics application.