Single crystal growth, magnetic and thermal properties of perovskite YFe0.6Mn0.4O3 single crystal

• High quality YFe0.6Mn0.4O3 single crystal was grown by floating zone technique.
• The thermal properties appear anomaly in the spin reorientation region.
• A clear spin reorientation transition behavior (Γ4→Γ1) is observed in the temperature range of 322–316 K, due to the substitution of Mn at the Fe site of YFeO3.

High quality YFe0.6Mn0.4O3 single crystal was grown by floating zone technique using a four-mirror-image-furnace under flowing air. Powder X-ray diffraction gives well evidence that the specimen has an orthorhombic structure, with space group Pbnm. Temperature dependence of the magnetizations of YFe0.6Mn0.4O3 single crystal were studied under ZFC and FC modes in the temperature range from 5 K to 400 K. A clear spin reorientation transition behavior (Γ4→Γ1) is observed in the temperature range of 322–316 K, due to the substitution of Mn at the Fe site of YFeO3. Its Néel temperature is around 385 K. Moreover, the spin reorientation is verified by the change of magnetic hysteresis loops of the sample along [001] axis in the temperature range of 50–385 K. The thermal properties of the sample were measured by the differential scanning calorimeter (DSC) from 300 K to 500 K, which also clearly appear anomaly in the spin reorientation region.