کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
180161 | 459372 | 2010 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Modification of a glassy carbon surface with amine-terminated dendrimers and its application to electrocatalytic hydrazine oxidation
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
Amine-terminated polyamidoamine (PAMAM) dendrimers were immobilized on glassy carbon electrodes (GCEs) via electrochemical oxidation of the terminal amine groups of dendrimers. The electrochemical immobilization of dendrimers was confirmed by cyclic voltammetry (CV) and X-ray photoelectron spectroscopy (XPS). The immobilized dendrimer films were robust and behaved as charge-selective electrochemical gates for oppositely charged redox molecules. The immobilization approach was applied to assemble Au dendrimer-encapsulated nanoparticles (Au DENs, dia. 1.5 ± 0.3 nm) on GCEs, and the resulting Au DEN films showed electrocatalytic activity to hydrazine oxidation.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochemistry Communications - Volume 12, Issue 6, June 2010, Pages 788–791
Journal: Electrochemistry Communications - Volume 12, Issue 6, June 2010, Pages 788–791
نویسندگان
Tae Hyun Kim, Hong Seok Choi, Byung Rye Go, Joohoon Kim,