کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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181633 | 459406 | 2008 | 4 صفحه PDF | دانلود رایگان |
The effects of electrochemical polarization on the micro-droplets formation were investigated using microscope observation method and electrochemical polarization techniques.It is found that cathodic polarization can initiate and accelerate the formation of micro-droplets, whereas anodic polarization can inhibit the micro-droplets formation, independent of metal type, electrolyte species, composition of air, and environmental humidity, indicating that the electrochemical polarization is the key condition for micro-droplets formation on metal surfaces. Based on above results, it is suggested that both the decrease of liquid/metal interface tension and the cooling of temperature of the three-phase-boundary area which are caused by cathodic polarization, may be the main reason for the micro-droplets formation.
Journal: Electrochemistry Communications - Volume 10, Issue 11, November 2008, Pages 1788–1791