کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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184917 | 459585 | 2014 | 5 صفحه PDF | دانلود رایگان |
Submicron-sized NiV3O8 powder was prepared by solid-state reaction method. A mixture of NiO, V2O5 and home-made VO2 (B) was used as starting material. The phase purity, structures, morphologies of the prepared powders were characterized by X-ray diffraction (XRD), scanning electronic microscopy (SEM) and X-ray photo-electron spectrometry (XPS), respectively. The results show that the as-prepared NiV3O8 material is highly crystalline and a single phase. The charge-discharge experiments were performed to investigate the electrochemical properties of NiV3O8 powder. NiV3O8 cathode delivers an initial discharge capacity of 286.6 mAh g−1 and still remains at 241 mAh g−1 after 30 cycles in the voltage of 1.5–4.2 V. The rate performance and EIS results indicate that the as-prepared electrode material has very good structural stability upon cycling after electrode conditioning by an initial charge and discharge.
Journal: Electrochimica Acta - Volume 148, 1 December 2014, Pages 261–265