کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
189646 | 459683 | 2011 | 9 صفحه PDF | دانلود رایگان |
Three double dithienylpyrroles derivatives have been successfully prepared by performing a Knorr–Paal condensation between 1,4-di(thiophen-2-yl) butane-1,4-dione and various aromatic diamines. Additionally, their corresponding polymer films were synthesized via electropolymerization. Their electrochemical, spectroelectrochemical and electrochromic behaviors were further investigated by thermogravimetric analysis, scanning electron microscopy, cyclic voltammetry, UV–vis absorption and fluorescence emission spectra. Scanning electron microscopy and thermogravimetric analysis demonstrated that the polymer films possessed homogeneous, compact and smooth layer structures and thermal stabilities (up to nearly 180 °C). Cyclic voltammograms and UV–vis absorption spectra studies showed that the polymer films have stable, well-defined, reversible redox processes, low optical band gaps (Eg < 2.2 eV) and multicolor electrochromic behaviors. Additionally, the fluorescence spectra study showed that all of the monomers and polymers exhibited different intensity emission bands at different wavelengths.
► Three kinds of double dithienylpyrroles derivatives have been successfully prepared by the Knorr–Paal condensation between 1,4-di(thiophen-2-yl) butane-1,4-dione and aromatic diamines.
► Their polymer films were successfully synthesized via electropolymerization.
► The polymer films had stable and well-defined reversible redox process, low optical band gap and multicolor electrochromic behavior.
► All the monomers and polymers exhibited different intensity emission bands at different wavelengths.
Journal: Electrochimica Acta - Volume 56, Issue 18, 15 July 2011, Pages 6352–6360