کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
191004 | 459712 | 2010 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Improved preparative electrochemical oxidation of d-glucose to d-glucaric acid
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Improved preparative electrochemical oxidation of d-glucose to d-glucaric acid Improved preparative electrochemical oxidation of d-glucose to d-glucaric acid](/preview/png/191004.png)
چکیده انگلیسی
The 2,2,6,6-tetramethyl-1-piperidinyloxy free radical (TEMPO) mediated electrochemical oxidation of d-glucose to d-glucaric acid on a synthetically useful scale is reported. Using TEMPO and a graphite felt anode combined with a stainless steel cathode, d-glucose was oxidized under different conditions (pH, temperature, co-oxidant), and the reaction outcomes were analyzed. Optimized conditions for such oxidation are provided along with few new interesting results unique to this reaction, such as the appearance of a novel triacid.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 55, Issue 10, 1 April 2010, Pages 3589–3594
Journal: Electrochimica Acta - Volume 55, Issue 10, 1 April 2010, Pages 3589–3594
نویسندگان
Mathias Ibert, Patrick Fuertès, Nabyl Merbouh, Catherine Fiol-Petit, Christian Feasson, Francis Marsais,