کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
192480 | 459743 | 2008 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Influence of underpotentially deposited Sb onto Pt anode surface on the performance of direct formic acid fuel cells
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
We first reported on electrocatalytic activity and stability of antimony modified platinum (PtSbupd) as anode catalyst in direct formic acid fuel cells. Sb modified Pt (PtSbupd) was prepared by underpotential deposition technique applying constant potential of 0.2 V (vs. Ag/AgCl, 3M KCl) and its modified surface was characterized by XRD and XPS. The electrocatalytic oxidation activity by cyclic voltammograms and the single cell power performance of Sb modified Pt were measured and their results were compared with the data of unmodified Pt electrode. PtSbupd induced lower onset potential of formic acid oxidation and twice higher power density of 250 mW cm−2 was observed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 53, Issue 21, 1 September 2008, Pages 6089–6092
Journal: Electrochimica Acta - Volume 53, Issue 21, 1 September 2008, Pages 6089–6092
نویسندگان
Jae Kwang Lee, Hongrae Jeon, Sunghyun Uhm, Jaeyoung Lee,