کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
196115 | 459832 | 2006 | 7 صفحه PDF | دانلود رایگان |
Novel hydrogen bonding diamide receptors viz., N,NI-bis(phenyl)iso phthalohydrazide (I) and N,NI-bis(2,4-dinitrophenyl)isophthalohydrazide (II), have been synthesized and characterized by IR, 1H NMR and elemental analysis. Spectroscopic investigations indicate high affinity of these receptors for carbonate ion. Polyvinyl chloride (PVC) based membranes of (I) and (II) using tridodecylmethylammonium chloride (TDDMACl) as cation discriminator and diethylphthalate (DEP), dioctylphthalate (DOP), 1-chloronapthalene (CN), tris(2-ethylhexyl)phosphate (TEHP) and bis(2-ethylhexyl)sebacate (DOS) as plasticizing solvent mediators were prepared and investigated as CO32− selective sensors. The best performance was shown by the membrane of composition (w/w) of (II) (4%):PVC (33%):CN (60%):TDDMACl (3%). This sensor works well over a wide concentration range 1.3 × 10−7 to 1.0 × 10−3 M with Nernstian compliance (29.0 mV decade−1 of activity) at pH 8.6 with a fast response time of ∼7 s and showed good selectivity for carbonate over a number of anions. The sensor exhibits adequate shelf life (two and half months) with good reproducibility (S.D. ± 0.3 mV) and could be used successfully for the determination of total inorganic carbon in water samples.
Journal: Electrochimica Acta - Volume 52, Issue 3, 12 November 2006, Pages 951–957