کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
201922 | 460577 | 2012 | 6 صفحه PDF | دانلود رایگان |
The solid–liquid equilibrium (SLE) of binary systems containing Alamine 304-1 (tri-dodecylamine), which used as a selective solvent in the extraction of molybdenum (Mo), was measured at atmospheric pressure by the visual method. The experimental SLE data for mixtures of Alamine 304-1 + 1-octanol, Alamine 304-1 + 2-octanol, and Alamine 304-1 + 1-decanol were then correlated to the non-random two-liquid (NRTL) and universal quasi-chemical (UNIQUAC) equations. We correlated the excess molar volume (VE) and deviations in molar refractivity (ΔR) of the aforementioned binary mixtures at 298.15 K using the Redlich–Kister equation. The VE and ΔR of the ternary mixtures Alamine 304-1 + 1-octanol + 2-octanol, Alamine 304-1 + 1-octanol + 1-decanol, Alamine 304-1 + 2-octanol + 1-decanol, and 1-octanol + 2-octanol + 1-decanol were predicted by the Radojkovič equation using the correlated binary Redlich–Kister parameters.
► Alamine 304-1 is selective solvent in the extraction of molybdenum (Mo).
► SLE data for the systems {Alamine 304-1 + 1-octanol}, {Alamine 304-1 + 2-octanol} and {Alamine 304-1 + 1-decanol}.
► NRTL and UNIQUAC models were used for the description of the determined SLE data.
► VE and ΔR the selectivities of the {Alamine 304-1 + 1-octanol}, {Alamine 304-1 + 2-octanol} and {Alamine 304-1 + 1-decanol} were measured.
Journal: Fluid Phase Equilibria - Volume 324, 25 June 2012, Pages 44–49