کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
205226 | 461101 | 2016 | 9 صفحه PDF | دانلود رایگان |
• Infrared radiated reactor rendered fast biodiesel yield from waste mustard oil.
• Infrared radiation resulted higher FAME yield & superior energy-efficiency than conventional heating.
• Amberlyst 15 catalyzed process optimization through Taguchi Orthogonal Design.
• B100 and its blend with petro-diesel rendered promising engine performance.
• Euro-6 exhaust emission norms are satisfied.
A novel protocol has been explored for fast and energy-efficient biodiesel production from waste mustard oil (WMO) using infrared radiated reactor in presence of heterogeneous Amberlyst 15 catalyst. High biodiesel yield (FAME content 97.13%) was obtained from WMO via simultaneous esterification–transesterification reactions in only 0.5 h using an energy-efficient, far infrared radiation (FIR) at the derived optimal conditions predicted through Taguchi Orthogonal Design (8:1 methanol to WMO molar ratio, 6 wt.% catalyst concentration, 800 rpm impeller speed). Experimental observations at the derived optimal conditions indicated much lower FAME yield (43.82%) with conventionally heated reactor even at the expense of 4 times energy input as that of FIR promoted protocol. Promising engine performance was observed at various blends of FIR produced optimal biodiesel with commercial petro-diesel. Notably, in comparison with petro-diesel, lower exhaust temperature was observed for all blends, indicating better engine durability and lower engine depreciation. The exhaust emissions measurements indicated that CO (0.05%) and hydrocarbon (HC) emissions (<0.00002) for B-100 were well below standard Euro-VI emission norms and were observed to decrease gradually with increase in biodiesel percentage in the blended fuel.
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Journal: Fuel - Volume 173, 1 June 2016, Pages 60–68