Density, viscosity, and N2O solubility of aqueous amino acid salt and amine amino acid salt solutions

Physicochemical properties of aqueous amino acid salt (AAS), potassium salt of sarcosine (KSAR) and aqueous amine amino acid salt (AAAS), 3-(methylamino)propylamine/sarcosine (SARMAPA) have been studied. Densities of KSAR were measured for sarcosine mole fraction 0.02 to 0.25 for temperature range 298.15 K to 353.15 K, the viscosities were measured for 0.02 to 0.10 mole fraction sarcosine (293.15 K to 343.15 K) while the N2O solubilities were measured from 0.02 to 0.10 mole fraction sarcosine solutions (298.15 K to 363.15 K). Densities of SARMAPA were measured for sarcosine mole fraction 0.02 to 0.23 for temperature range (298.15 K to 353.15 K), viscosities were measured for 0.02 to 0.16 mole fraction sarcosine (293.15 K to 343.15 K) while the N2O solubilities were measured from 0.02 to 0.16 mole fraction sarcosine solutions (298.15 K to 343.15 K). Experimental results were correlated well with empirical correlations and N2O solubility results for KSAR were predicted adequately by a Schumpe model. The solubilities of N2O in AAS and AAAS are significantly lower than values for amines. The solubilities vary as: amine > AAAS > AAS.

► Density of amino acid salt and amine amino acid salt.
► Viscosity of amino acid salt and amine amino acid salt.
► Henry’s law constant/N2O solubility of amino acid salt and amine amino acid salt.
► Schumpe model. Correlations for density, viscosity, and N2O solubility.