کد مقاله کد نشریه سال انتشار مقاله انگلیسی ترجمه فارسی نسخه تمام متن
26181 43938 2016 6 صفحه PDF ندارد دانلود رایگان
عنوان انگلیسی مقاله
Photocatalytic organic syntheses using a glass-milled microchip
ترجمه فارسی عنوان
سنتز آلیاژهای فوتوکاتالیستی با استفاده از یک میکروچاپ شیشه ای
کلمات کلیدی
سنتز آلی فوتوکاتالیستی؛ ریزتراشه؛ نیتروبنزن. آنیلین؛ ایمین
Photocatalytic organic synthesis; Microchip; Nitrobenzene; Aniline; Imine
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی بیو مهندسی (مهندسی زیستی)
چکیده انگلیسی


• A glass-milled microchip is proposed for photocatalytic organic syntheses.
• Oxidation and reduction reactions for aromatic compounds are demonstrated.
• Imine is synthesized using a multi-step reaction.
• Photocatalytic microchip can be used more than 300 times.

Photocatalytic reactions, typically known as difficult to control due to secondary reactions and involvement of multiple radicals, were demonstrated to be controlled well by optimizing the reaction time and the microchip design. The glass-milled microchip has a good resistivity for the organic solutions and withstands multiple usage more than 100 times. The oxidization and reduction reactions were demonstrated and the flow considerably improved the conversion and yield. Furthermore, an imine synthesis was demonstrated as a multi-step reaction by combination of photocatalytic oxidation and reduction reactions.

Graphical abstractA glass-milled microchip is proposed for photocatalytic organic syntheses, which could be used more than 300 times, and oxidation and reduction reactions for aromatic compounds, multi-step reaction for imine synthesis were demonstrated.Figure optionsDownload full-size imageDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volumes 322–323, 15 May–1 June 2016, Pages 35–40
نویسندگان
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