کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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28812 | 44093 | 2011 | 5 صفحه PDF | دانلود رایگان |
A benzoxadiazole–thiourea conjugate (1) was synthesized and used for chemodosimetric detection of Hg2+ in aqueous media. The compound 1 shows a selective and quantitative fluorescence quenching upon addition of Hg2+. This is promoted via a Hg2+-induced desulfurization of the thiourea moiety, leading to a formation of an imidazoline derivative, 2. Ab initio molecular orbital calculation reveals that the formation of imidazoline moiety by the reaction of 1 with Hg2+ promotes a photoinduced electron transfer from the aniline moiety to the excited state benzoxadiazole moiety and results in fluorescence quenching.
A benzoxadiazole–thiourea conjugate (1) shows selective and quantitative fluorescence decrease upon Hg2+ addition in aqueous media. The fluorescence decrease is promoted by a Hg2+-induced desulfurization of the thiourea moiety, leading to a promotion of intramolecular photoinduced electron transfer from the aniline moiety to the excited state benzoxadiazole moiety.Figure optionsDownload as PowerPoint slide
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 219, Issue 1, 5 March 2011, Pages 154–158