The oxygen isotopic composition of uranium minerals: A review

Uranium ore is an essential material in the preparation of nuclear fuel for civilian as well as military uses. Uranium is first extracted from uranium-bearing minerals using a variety of reagents, and is precipitated from solutions as yellow cake prior to isotope enrichment processes. The disintegration of the former Eastern Bloc in the 1990s and frequent unrest in the Middle East have underscored the need for better characterizing source uranium ores for forensic and attribution purposes.The world's major deposits of U occur in several distinctly different geological environments. Fourteen principal types of U deposits and rocks with elevated uranium contents are recognized with more than 40 subtypes. Combining our own analysis and literature data, we have amassed over 250 oxygen isotope data from 13 major U-producing countries, which vary widely from − 32 to + 11‰. However, interpreting the oxygen isotopic composition of uraninite in terms of the composition of the fluid from which it precipitated, or interacted with, requires knowledge of the fractionation factor and temperature of interactions, which are not always available. Since each deposit type occurs within a unique geologic setting and is generally formed from chemically distinct fluids, the chemical compositions of the uranium ores are also distinct: uranium deposits that form in igneous rocks have higher trace element compositions relative to sandstone-hosted deposits. Our data shows that one of the most useful techniques for distinguishing between uranium ore is to use a combination of δ18O values and rare-earth elements (e.g., La/Yb ratios). These methods may allow investigators to trace uranium ore back to the source.

► We have amassed over 250 oxygen isotope data from 13 major U-producing countries.
► δ18O values of uranium minerals range from – 34 to + 12‰, with uraninite being one of the most 18O depleted minerals.
► δ18O values of yellow cakes and fuel pellets could be used to infer their locations of production, rather than the original δ18O values of U-ores.
► The most useful techniques for distinguishing between uranium ores is to use a combination of d18O values and rare-earth elements.