کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
4762661 1422944 2018 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Biomass-facilitated production of activated magnesium oxide nanoparticles with extraordinary CO2 capture capacity
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Biomass-facilitated production of activated magnesium oxide nanoparticles with extraordinary CO2 capture capacity
چکیده انگلیسی
Discovering sustainable materials that can efficiently capture and store CO2 is a crucial step towards mitigating anthropogenic greenhouse gas emissions. The current materials used in post-combustion scenarios have significant drawbacks, including high cost and resulting hazardous byproducts. This study developed a simple and cost-effective method of producing activated MgO nanoparticles that have high CO2 capture efficiency. To optimize CO2 capture, we incorporate biomass during the production to ensure complete and dispersed MgO nanoparticle formation from the decomposition of MgCl2 hydrate. Materials are characterized by SEM, XRD, BET/DFT, ICP, and TGA analysis. Resulting carbon-supported activated MgO nanoparticles efficiently captured CO2 at low temperature, by physisorption and magnesium carbonate formation. Without the incorporation of biomass, MgCl2 hydrate decomposed via low temperature pyrolysis, is still capable of CO2 capture; however, the efficiency is enhanced with the addition of biomass, as this helps support the formation and distribution of MgO nanoparticles. The carbon-supported MgO nanoparticles produced with a 5:2.5 (w/w MgCl2:biomass) ratio was capable of greatest CO2 capture capacity on both a g−1 material (up to 235 mg g−1) and g−1 magnesium (733 mg g−1) basis after 3 h. The carbon-supported MgO nanoparticles have potential to be applied in inexpensive large-scale CO2 capture, as the production can be adjusted based on capacity, resource, or energy constraints.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Journal - Volume 334, 15 February 2018, Pages 81-88
نویسندگان
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