کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4766664 | 1424102 | 2017 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Sandwich-type Bimetal-Organic Frameworks/Graphene Oxide Derived Porous Nanosheets doped Fe/Co-N Active Sites for Oxygen Reduction Reaction
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
In this work, a bimetal-organic framework/graphene oxide with sandwich-type structure as a precursor is prepared by the solvent-thermal approach. A nanoporous reduced graphene oxide (rGO) nanosheets enriched with Fe, Co and N (Fe/Co-N) co-doped active sites is prepared followed by a high temperature carbonization and acid leaching (AL) process. When the molar ratio of Fe/Co is 0.40 before carbonization, the prepared sample exhibits optimized electrocatalytic activity (a high onset potential (0.98Â V vs. RHE), half-wave potential (0.84Â V vs. RHE), and a large limiting current density (-5.46Â mAÂ cmâ2 at 0.21Â V vs. RHE) as oxygen reduction reaction (ORR) electrocatalysts. Most importantly, the duration stability and methanol tolerance of the as-prepared sample are better than common commercial 20Â wt% Pt/C under 0.10Â M KOH alkaline condition. These results demonstrate the co-doping of bimetal Fe/Co and heteroatom N, excellent electrical conductivity of rGO and large surface area of nanoporous structure enhance the electrocatalytic activity. The successful synthesis of such nanoporous rGO nanosheets provides a facile way to explore a series of 2D non-precious metal electrocatalysts for energy conversion and storage devices.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 255, 20 November 2017, Pages 72-82
Journal: Electrochimica Acta - Volume 255, 20 November 2017, Pages 72-82
نویسندگان
Qijian Niu, Junxia Guo, Yunhui Tang, Xindong Guo, Jun Nie, Guiping Ma,