کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4767608 | 1424131 | 2017 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
High-performance CuO/Cu composite current collectors with array-pattern porous structures for lithium-ion batteries
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The surface structure and material composition of current collectors significantly affect the electrochemical performances of lithium-ion batteries. This study forms array-pattern blind holes and creates a layer of copper oxide (CuO) on the surface of thin copper plates using the chemical etching method. This copper plate is made into a CuO/Cu composite current collector with array-pattern porous structures for lithium-ion batteries. Using mesocarbon microbead graphite powders as the anode material, this new composite current collector is assembled into CR2032 coin half-cells for electrochemical tests. Batteries with this porous current collector exhibit high reversible discharge capacities of 383.9 mAh gâ1 at 0.5 mA and 374 mAh gâ1 even after 0.2C and 0.5C rate cycles, whereas batteries with a complanate current collector deliver only 309.6 mAh gâ1 and 296.7 mAh gâ1. It is believed that the array-pattern blind holes coupled with the morphological effects of the oatmeal-like CuO significantly enhance the electrochemical performances of batteries in terms of reversible capacity, cycling stability, electrical conductivity and coulombic efficiency.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 226, 1 February 2017, Pages 89-97
Journal: Electrochimica Acta - Volume 226, 1 February 2017, Pages 89-97
نویسندگان
Wei Yuan, Jian Luo, Zhiguo Yan, Zhenhao Tan, Yong Tang,