کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
4907220 1426197 2018 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Thermodynamics of neptunium(V) complexation with sulfate in aqueous solution
ترجمه فارسی عنوان
ترمودینامیک کمپلکس دهنده نپتونیوم (V) با سولفات در محلول آبی
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
چکیده انگلیسی


- Complexation of NpO2+ with SO42− is studied as a function of T and Im by UV/Vis/NIR.
- log β0(T), ΔrH0m, ΔrS0m is determined at IUPAC reference state.
- The ionic strength dependence is described by the SIT and εj,k(T) is calculated.

The complexation of NpO2+ with sulfate is studied in aqueous solution using absorption spectroscopy. The total ligand concentration (Na2SO4), ionic strength (NaClO4), and temperature (T = 20-85 °C) is varied, yielding detailed information on the thermodynamics of the complexation reaction. A single complex species (NpO2(SO4)−) is identified by peak deconvolution of the absorption spectra. The molar fraction of the complex species increases with increasing temperature. The conditional stability constants log β′1(T) are calculated and extrapolated to zero ionic strength for each temperature condition with the specific ion interaction theory (SIT). The determined log β01(T) values increase by approximately one logarithmic unit in the studied temperature range. Furthermore, the log β01(T) values are linearly correlated with the reciprocal temperature. Thus, fitting the data according to the integrated Van't Hoff equation yields the standard reaction enthalpy (ΔrH0m) and entropy (ΔrS0m) of the formation of the NpO2(SO4)− complex. The results show an endothermic reaction which is solely driven by the reaction entropy. In addition, the binary SIT ion-ion interaction coefficient ε(Na+, NpO2(SO4)−) of the complex species is determined.

67

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: The Journal of Chemical Thermodynamics - Volume 116, January 2018, Pages 309-315
نویسندگان
, , , , ,