کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4907860 | 1426581 | 2017 | 8 صفحه PDF | دانلود رایگان |
- Performance of DSSC with PANI composite counter electrode is akin to PT cells.
- VOC of DSSC is dependent on the reduction potential of redox couples in electrolytes.
- Jsc of DSSC is dependent on the reduction current density of redox couples.
Polyaniline (PANI)/graphene nanoplatelet (GNP)/multi-walled carbon nanotube (MWCNT) composite films deposited on fluorine-doped tin oxide (FTO) substrates were successfully fabricated through electrochemical method without pre-treatment of GNP and MWCNT to provide a lower cost counter electrode (CE) for dye-sensitized solar cells (DSSCs). By varying the contents of GNP and MWCNT in the PANI composite CE, the short-circuit current density of DSSC was found to linearly relate to the reduction current density of Iâ/I3â redox couples measured by cyclic voltammetry. The open-circuit voltage (VOC) is also highly dependent on the reduction potential of redox couples. Besides, the charge transfer resistance at the electrolyte/CE interface measured by electrochemical impedance spectroscopy has an approximately linear relationship with the sheet resistance of PANI composite CE. Notably, the DSSC with the CE fabricated by the weight ratio of PANI/GNP/MWCNT at 1:0.003:0.0045 yielded the highest power conversion efficiency of 7.67 ± 0.05%, which is comparable with the conventional Pt cell (7.62 ± 0.07%).
The counter electrode for DSSC with polyaniline/graphene/MWCNT composite prepared by electrochemical deposition method showed the excellent performance comparable to the Pt cell.137
Journal: Journal of Electroanalytical Chemistry - Volume 794, 1 June 2017, Pages 112-119