کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4908253 | 1426593 | 2016 | 16 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Preparation and performance of Li4C10H4O8 with multi-carboxyl groups as anode material for lithium-ion batteries
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
In this work, a naphthalene tetracarboxylic acid lithium salt (NTCLi) as anode material is designed for lithium-ion batteries, with high theoretical capacity and conjugated system according to the combination principles of multi-carboxyl groups and low molecular weight, which is prepared through a simple one-pot neutralization reaction. The sample is characterized by SEM, TEM, XRD, IR and TGA. The results show that NTCLi exhibits nanorod-like structure, well thermal stability and crystalline structure. The electrochemical measurements results demonstrate the initial discharge capacity of 276 mAh gâ 1 with low discharge platform (~ 0.9 V) at the current density of 0.1 C are achieved for NTCLi, and the discharge specific capacity of 190 mAh gâ 1 can be retained after 100 cycles. Also, NTCLi delivers good rate capability with discharge capacity of up to 112 mAh gâ 1, even at a current density as high as 2 C, indicating the as-prepared sample could be a promising candidate as anode materials for lithium-ion batteries.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Electroanalytical Chemistry - Volume 782, 1 December 2016, Pages 202-206
Journal: Journal of Electroanalytical Chemistry - Volume 782, 1 December 2016, Pages 202-206
نویسندگان
Xiaoyun Yang, Zuyan Liu, Xiaodian Chen, Wenbin Wang, Xiaoju Chen, Zilin Yuan, Hebing Zhou, Ronghua Zeng, Yifan Luo,