|کد مقاله||کد نشریه||سال انتشار||مقاله انگلیسی||ترجمه فارسی||نسخه تمام متن|
|49687||46760||2016||4 صفحه PDF||ندارد||دانلود رایگان|
• Increasing MgO loading leads to the increased ratio of Lewis acid sites to Brönsted ones.
• The suitable ratio of medium and strong Lewis acid sites to medium and strong Brönsted ones is about 1.
• The suitable optimum ratio of total Lewis acid sites to total Brönsted ones is 2–3.
• Formation of coke with lower H/C ratio is the main factor accounting for catalyst deactivation.
On-stream stability of fluid catalytic cracking (FCC) naphtha hydro-upgrading catalysts that convert olefins into high-octane isoparaffins and aromatics is crucial for guaranteeing the long-term operation of industrial units, and therefore suppressing catalyst deactivation due to coking becomes the focus of FCC naphtha hydro-upgrading process and catalyst development. Here we report a simple and novel strategy to enhance the on-stream stability of a HZSM-5 based FCC naphtha hydro-upgrading catalyst by magnesium modification. The characterization and catalytic test results showed that the incorporation of a suitable amount of MgO can adjust the ratio of Lewis acid sites to Brönsted ones and thereby significantly improve stability of the resulting catalyst.
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Journal: Catalysis Communications - Volume 83, 5 August 2016, Pages 31–34