کد مقاله کد نشریه سال انتشار مقاله انگلیسی ترجمه فارسی نسخه تمام متن
49947 46774 2016 4 صفحه PDF ندارد دانلود رایگان
عنوان انگلیسی مقاله
Transfer hydrogenation of methyl levulinate into gamma-valerolactone, 1,4-pentanediol, and 1-pentanol over Cu–ZrO2 catalyst under solvothermal conditions
ترجمه فارسی عنوان
هیدروژناسیون انتقالی متیل لووولینت به گاما والرولاکتون، 1،4-پنتانیدیول و 1-پنتانول بر روی کاتالیزور Cu-ZrO2 تحت شرایط solvothermal
کلمات کلیدی
شرایط سولوتوترمال؛ ایسپروپانول؛ کاتالیزور مس زیرکونیم؛ متیل لووالینت؛ هیدروژناسیون انتقالی
Solvothermal conditions; Isopropanol; Copper–zirconium catalysts; Methyl levulinate; Transfer hydrogenation
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
چکیده انگلیسی


• A simple solvothermal method was introduced into the sequential conversion of methyl levulinate (ML).
• Various yields of diverse products were obtained by tuning a series of factors.
• Catalyst 2.5-CZ-550 showed a better performance because of its rich acid content and Cu0 species on the surface.

Diverse products were obtained from transfer hydrogenation of methyl levulinate (ML) by adjusting different factors under solvothermal conditions. Excellent yields of gamma-valerolactone (GVL, 75%), 1,4-pentanediol (1,4-PDO, 39%), and 1-pentanol (1-PAO, 13.8%) could be obtained using zirconium-supported copper catalyst calcined at 550 °C and under optimal conditions.

Graphical abstractRelatively mild and operational solvothermal conditions were used for hydrogenation of ML to GVL, 1,4-PDO, and 1-PAO over zirconium-supported copper catalysts.Figure optionsDownload full-size imageDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Communications - Volume 76, 10 February 2016, Pages 50–53
نویسندگان
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