کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5010093 | 1462050 | 2017 | 7 صفحه PDF | دانلود رایگان |
- Fluorogenic type hypochlorite-selective probe was developed for tap water analysis.
- Signaling was based on hypochlorite-triggered oxidative hydrolysis of sulfonhydrazone.
- Selective sensing over other oxidants was possible with a detection limit of 20Â nM.
- The probe could conveniently determine hypochlorites in tap water using a smartphone.
A new hypochlorite-selective fluorescence signaling probe based on the sulfonhydrazone of 2-acetyl-6-methoxynaphthalene was investigated. The probe was easily prepared by the simple one-step reaction of 2-acetyl-6-methoxynaphthalene with p-toluenesulfonylhydrazide. The probe exhibited off/on-type fluorescence signaling behavior toward hypochlorite in aqueous solution via hypochlorite-triggered oxidative hydrolysis of the sulfonhydrazone to yield strongly fluorescent 2-acetyl-6-methoxynaphthalene. Selective hypochlorite signaling over other common oxidants with a large fluorescence enhancement (76-fold) was possible, with a detection limit of 2.0Â ÃÂ 10â8Â M. Hypochlorite signaling was not affected by the presence of other common metal ions or representative anions. As a practical application, the methoxyacetylnaphthalene sulfonhydrazone probe was used to determine hypochlorite levels in a tap water sample using a standard smartphone as the detection tool.
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Journal: Sensors and Actuators B: Chemical - Volume 241, 31 March 2017, Pages 285-291