کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5149566 | 1497885 | 2017 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Calcium-doped ceria materials for anode of solid oxide fuel cells running on methane fuel
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A calcium-doped ceria with nominal compositions of Ce1-xCaxO2-δ (0.00 â¤Â x â¤Â 0.30) has been developed as an anode component for solid oxide fuel cells running on methane fuel. Crystal phases of Ce1-xCaxO2-δ are investigated with respect to the amount of calcium dopant. The Ce1-xCaxO2-δ shows single fluorite phase when the calcium is within 15 mol.%, and higher calcium doping levels lead to the appearance of a secondary phase (CaO). Conductivities of Ce1-xCaxO2-δ ceramics are studied by a four-probe method in air and the composition of Ce0.9Ca0.1O2-δ (x = 0.10) is found exhibiting the highest conductivity among the samples investigated in this work. Electrocatalytic properties of Ce0.9Ca0.1O2-δ are evaluated based on Ni-Ce1-xCaxO2-δ anode supported single cell running on methane fuel. At 800 °C, the single cell with Ni-Ce0.9Ca0.1O2-δ (x = 0.10) anode exhibits an optimum maximum powder density (618 mW cmâ2) and good performance stability during 30 h operation in methane fuel. The promising findings substantiate the good performance of Ni-Ce0.9Ca0.1O2-δ anode for electrochemical oxidation of methane fuel.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 347, 15 April 2017, Pages 79-85
Journal: Journal of Power Sources - Volume 347, 15 April 2017, Pages 79-85
نویسندگان
Kai Zhao, Yanhai Du,