کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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5187065 | 1381120 | 2008 | 9 صفحه PDF | دانلود رایگان |
This paper reports the preparation of a MAMA-SG1 (BlocBuilderâ¢) derived alkoxyamine bearing a N-succinimidyl (NHS) ester group 1, valuable for functional and advanced polymer synthesis. This alkoxyamine was exploited following two strategies: (i) a post-functionalization approach based on the transformation of α-NHS chain ends of polymers previously obtained by nitroxide mediated polymerization (NMP) from 1 (path A) and (ii) a pre-functionalization approach based on the functionalization of alkoxyamine 1 prior to NMP (path B). Path A was demonstrated by derivatization of α-NHS functionalized polystyrenes with ethanolamine, yielding hydroxyl-functionalized polystyrenes. Path B was illustrated by two examples: first, a OH functional alkoxyamine initiator, prepared by reaction of 1 with ethanolamine, was used for the synthesis of polystyrene-b-poly(d,l-lactide) by combining NMP and ring-opening polymerization. Secondly, a poly(propylene oxide)-SG1 macroalkoxyamine, obtained from reaction of 1 with NH2-functionalized poly(propylene oxide), was used as a macroinitiator for NMP of styrene to obtain a PS-b-PPO block copolymer.
Journal: Polymer - Volume 49, Issue 17, 11 August 2008, Pages 3639-3647