کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5210591 | 1382904 | 2011 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Polydimethylsiloxane/liquid crystal cross-linked membranes: Preparation, characterization and oxygen transport properties
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The introduction of liquid crystals (LCs) has presented an interesting approach to improving gas separation properties in polymeric membranes. A novel polydimethylsiloxane (PDMS)/LC cross-linked membrane was prepared with PDMS containing vinyl groups and LCs containing unsaturated linkages as matrix materials. The chemical structures and LC properties were characterized with FTIR, DSC and thermal polarized optical microscopy. Some influential factors that affect the permeability and transport properties were also studied. The results showed that the membranes exhibited good transport properties. The oxygen permeability coefficient and oxygen/nitrogen separation factor were as large as 789Â Barrer and 3.40, respectively. The transport properties of the membrane are significantly larger than those of Robeson's upper bound. Compared with modified PDMS membranes, the cross-linking method and the introduction of LCs are simple and convenient, and the transport properties are also enhanced.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Reactive and Functional Polymers - Volume 71, Issue 5, May 2011, Pages 537-543
Journal: Reactive and Functional Polymers - Volume 71, Issue 5, May 2011, Pages 537-543
نویسندگان
Huaxin Rao, Ziyong Zhang, Chen Song, Tao Qiao,