کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5210825 | 1382919 | 2008 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis and characterization of poly (2-hydroxyethyl methacrylate)-polyaniline based hydrogel composites
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
In this report, the synthesis and characterization of poly (2-hydroxyethyl methacrylate)-polyaniline-polyaniline (p-HEMA-PANi) hydrogels were investigated. The hydrogels were synthesized using: 2-Hydroxyethyl methacrylate (HEMA), N-Tris (hydroxymethyl) methyl] acrylamide, 3-Sulfopropyl methacrylate potassium salt, Tetraethylene glycol diacrylate, Poly-(2-hydroxyethyl methacrylate), 2,2-Dimethoxy-2-phenylacetophenone and aniline by UV irradiation. Two sets of the hydrogels were prepared using water/1, 3, 3, 3-(tetramethyl butyl phenyl polyethylene glycol [Triton X-100] and water/ethylene glycol as the solvent. Scanning electron microscopy (SEM) revealed a more uniform pore size when Triton X-100 (TX-100 HG) was used as compared to ethylene glycol (EG-HG). Thermogravimetric analysis (TGA) showed that both hydrogels were stable upto 270 °C. Fourier transform-Infra red (FT-IR) spectrum confirmed the incorporation of polyaniline (PANi) and HEMA in the composite. Electrochemical properties of the hydrogels evaluated using Cyclic Voltammetry and Electrochemical Impedance Spectroscopy (EIS) demonstrated the electroactivity and conductivity of the hydrogels.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Reactive and Functional Polymers - Volume 68, Issue 8, August 2008, Pages 1239-1244
Journal: Reactive and Functional Polymers - Volume 68, Issue 8, August 2008, Pages 1239-1244
نویسندگان
Joseph H.O. Owino, Omotayo A. Arotiba, Priscilla G.L. Baker, Anthony Guiseppi - Elie, Emmanuel I. Iwuoha,