کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5212260 | 1383109 | 2017 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Reaction of N-heterocyclic carbaldehydes with furanones – An investigation of reactivity and regioselectivity
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The aldol reaction of N-heterocyclic carbaldehydes with furan-2-ones has been investigated. Very mild and metal-free reaction conditions have been applied. The substitution pattern of the product was found to be controlled by the aldehyde. A detailed investigation of the reactivity has been performed and the surprising regio- and diastereoselectivity has been elucidated with the help of 2D-NMR techniques. Here, we report on a convenient way to N-donor functionalized lactones, which had scarcely been examined before.
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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron - Volume 73, Issue 30, 27 July 2017, Pages 4472–4480
Journal: Tetrahedron - Volume 73, Issue 30, 27 July 2017, Pages 4472–4480