کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5213041 1383143 2017 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Rational synthesis and comparative investigation on a series of fluorinated aryl substituted diketopyrrolopyrrole
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Rational synthesis and comparative investigation on a series of fluorinated aryl substituted diketopyrrolopyrrole
چکیده انگلیسی

We novelly designed and synthesized a set of fluorinated diphenyl-diketopyrrolopyrrole (DPP) compounds by varying the position and amount of fluorine atom, and to the best of our knowledge, it is the first time a difluoromethyl group and perfluoroalkyl chains had been introduced into the DPP unit in good yields. We investigate the optical/electrochemical properties of all the compounds. Density functional theory (DFT) calculations were applied to explore orbital energy value of these compounds. The results demonstrated that the perfluorocarbon chains substituted DPPs with larger red-shift in both absorption and emission spectra and narrower bandgap.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Tetrahedron - Volume 73, Issue 5, 2 February 2017, Pages 494-499
نویسندگان
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